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Pot Life - Part 4 of 5
Posted on 5/24/2010 in Commercial & Industrial CoatingsNew Application TechniquesThe Green InitiativeDecorative ConcreteSystem Design

Author Peter Collins

As is the case with a lot of chemistry terms, we get the word POLYMER from a combination of two Greek words. The first is POLY, meaning "many" and the second is MEROS, which means "part". In the floor coating industry, the term polymer has loosely come to be used to include single-component materials. But, it is more appropriately used when referring to liquid thermoset coating materials like epoxy or polyurethane.

The short definition of a polymer floor coating’s pot life is, the amount of time that the coating material remains in a fluid liquid state, allowing for its proper application onto a given floor substrate.

As the above definition indicates, a coating’s pot life is measured in terms of time. Specifically, it’s the amount of time that elapses from the moment the liquids are mixed until the moment that the mixture is no longer fluid enough to be applied to the substrate, as intended. Often, terms which are associated with a coating’s pot life, will be used interchangeably and, for the person who is new to the world of coatings or for professionals who may have gotten their coatings education on the fly, the simple concept of a material’s pot life can sometimes become unnecessarily murky. So, for the sake of clarity, following are the practical basics with respect to a polymer coating’s pot life.

A high performance polymer floor coating will, more often than not, be comprised of two liquid-state materials, which become the actual coating once they’ve been combined. The two separate liquids are usually supplied as a unit called a “kit”. The two components of the kit are usually referred to as parts “A” and “B”. Most formulating manufacturers refer to the resin portion of the kit as Part A and the activator as Part B. The activator is also called a hardener, a curing agent or a catalyst.

When a predetermined amount of polymer floor coating resin is thoroughly mixed with a designated amount of its corresponding catalyst (a combination called the mix ratio), the two react and form three-dimensional crosslinking carbon molecule bonds throughout the coating’s structure. The crosslinking process starts as soon as the resin and its hardener are mixed.

As crosslinking evolves and begins to cure, the coating material’s viscosity increases. The lower a coating material’s viscosity is, the more fluid it is. The higher its viscosity, the less fluid and more rigid it will be. As an example, water has a low viscosity level and maple syrup and Silly Putty both have higher viscosity levels. The coating material's pot life comes to an end when proper application of the coating is no longer possible due to a loss of the material’s fluidity and an increase in its viscosity. 

The pot life of a polymer coating will be influenced (faster or slower) depending on five basic variables: 
  1. The chemical formulation of the material. 
    Coatings can be formulated to either increase or decrease pot life and cure times.

  2. The temperatures of the coating material, application environment and of the substrate.
    Higher temperatures will shorten and lower temperatures will lengthen a coating’s pot life.

  3. The ambient relative humidity.
    An increase in humidity can increase pot life and a decrease in humidity will decrease pot life.

  4. The amount of materials that are mixed together at one time (volume).
    Greater amounts of material mixed together at one time will shorten  pot life while lower amounts will allow for a longer pot life.

  5. The use of retarders or accelerators.
    These types of additives can be incorporated into the coating material at the point of mixing and can effectively slow down or speed up the coating material’s pot life as needed. 
Some other terms that are sometimes used instead of pot life are:
-     Application Time
-     Open Time
-     Pour Time
-     Spreadable Life
-     Spreadable Time
-     Usable Life
-     Usable Time
-     Wet Time
-     Work Time 

After a coating’s pot life has been reached, it passes through three basic curing stages: 

  1. Gel Time
    This marks the point in a cure when the mix is incapable of flow.

  2. Tack Time
    The intermediate point between a coating’s liquid state (wet) and its solid state (cured). During this stage, the coating will feel sticky.

  3. Cure Time
    This is the amount of time it takes a coating material to first become tack-free and then to reach a fully cured state. A floor coating’s full cure will typically be reached over the course of various days. 

If you don’t already do so, start to make a habit of using both the term and the concept of pot life when planning a floor coating application. It should be your first point of reference for the amount of time that you have to apply the coating once the components are mixed together. Not knowing a polymer material’s pot life can lead to aesthetic, adhesive and other coating defects which, in turn can cascade into loss of time, revenue, confidence and other related problems. Always consult the coating manufacturer’s guidelines and make allowances for the variables indicated above.



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